Chemical Reactions in Ionic Matrices

Catalytic reactions in ionic liquids.

The chemical industry is under considerable pressure to replace many of the volatile organic compounds (VOCs) that are currently used as solvents in organic synthesis. The toxic and/or hazardous properties of many solvents, notably chlorinated hydrocarbons, combined with serious environmental issues, such as atmospheric emissions and contamination of aqueous effluents is making their use prohib...

Efficient Sustainable Tool for Monitoring Chemical Reactions and Structure Determination in Ionic Liquids by ESI-MS

An easy and convenient procedure is described for monitoring chemical reactions and characterization of compounds dissolved in ionic liquids using the well-known tandem mass spectrometry (MS/MS) technique. Generation of wastes was avoided by utilizing an easy procedure for analysis of ionic liquid systems without preliminary isolation and purification. The described procedure also decreased the...

Influence of Ionic Liquids on Physico Chemical Reactions Reactions of Excited-State Benzophenone Ketyl Radical in a Room-Temperature Ionic Liquid

The photochemistry of benzophenone ketyl radical in the D1 excited state, BPH(D1), was studied by means of two-color dual-pulse laser flash photolysis (355 and 532 nm) in a room-temperature ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide (Bmim-TFSA), and in methanol. Upon excitation with the 532-nm pulse, BPH(D1) emitted strong fluorescence. The transient absorption ...

Chemical reactions.

Protease-Catalyzed Synthetic Reactions in Ionic Liquids

Enzymes are very effective and biodegradable catalysts, and act under mild conditions such as room temperature, atmospheric pressure, and around pH 7. Consequently, the applications of enzymes to the organic synthesis have extensively been studied from the standpoint of the development of sustainable synthetic processes (Truesdell, 2005). Enzymes exhibit the high activity and specificity not on...